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Thank you for visiting nature. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser or turn off compatibility mode in Internet Explorer. In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript. A Nature Research Journal. Understanding the distribution of parent Re and radiogenic daughter Os isotopes in molybdenite is critical in interpreting isotopic measurements because it can compromise the accurate determination and interpretation of mineralization ages.

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Due to the geometry of the mass spectrometer, it was not possible to collect all the relevant isotopes simultaneously, thus each area was mapped twice using two different configurations of the multicollection system. The magnetic field was fixed, and the electron multiplier EM detectors were positioned to collect signal from 56 Fe, 63 Cu, 98 Mo, Ag, Re, Os during the first run, and then the last two detectors were moved to collect Re and Os during the second run.

The peak positions were calibrated using pure Re and Os metal standards.

Mar 25,   Abstract [1] Eleven core samples of Ordovician carbonates and shale from within and nearby the Serpent Mound (Ohio) cryptoexplosion structure were analyzed for Re-Os isotopes. Whole-rock samples span a large range in measured Os/ Os ( to ), and exhibit a linear correlation of Os/ Os with Re/ Os. The linear relationship is inconsistent with a . The Re-Os isotopic system is particu-larly powerful where the age of Re-bearing mineral phases can be related to discrete episodes of hydrother-mal activity. The mineral most widely used for Re-Os dating is molybdenite (MoS2) because it contains low ppm to percent concentrations of Re and only ppt amounts of initial, non-radiogenic Os. Rhenium-osmium dating is a form of radiometric dating based on the beta decay of the isotope Re to normally occurs with a half-life of ? 10 9 y, but studies using fully ionised Re atoms have found that this can decrease to only 33 y. Both rhenium and osmium are strongly siderophilic (iron loving), while Re is also chalcophilic (sulfur loving) making it useful in.

As sensitivity was a key issue and there were no significant mass interferences, no slits were used in the mass spectrometer. McCandless, T. Rhenium-Osmium evidence for regional mineralization in southwestern North-America.

Science- Barra, F. Kirk, J. A major Archean, gold- and crust-forming event in the Kaapvaal craton, South Africa.

Mathur, R. Relationship between copper tonnage of Chilean base-metal porphyry deposits and Os isotope ratios. Geology 28- Stein, H.

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The remarkable Re-Os chronometer in molybdenite: how and why it works. Terra Nova 13- Herr, W. Hintenberg, H.

Re-Os dating of chalcopyrite from selected mineral deposits in the Kalatag district in the eastern Tianshan Orogen, China. They contain common Os ranging from to ppt and have Re/ Os ratios between and Cited by: The Re-Os isotopic determination in oil and similar samples is still under investigation to understand the meaning of ages and initial Os/ Os isotopic et al. evaluated. Therefore, the Re-Os geochronometer can be used for dating the formation age of ore samples directly, and the Re-Os age will represent the true mineralization age of an ore deposit. In addition, Re is more highly concentrated in crustal rocks than Os when compared to the mantle, because Re is more incompatible than Os during mantle melting Author: Cheng-Cheng Huang, Hai-Feng Guo, Jie Li, Qiang Wang, Qiang Wang, Chunfu Zhang, Derek Wyman, Gong-Jia.

Half-life of rhenium. Luck, J. The study of molybdenites through the Re- Os chronometer. Earth Planet. Rhenium behavior in molybdenite in hypogene and near-surface environments: implications for Re-Os geochronology.

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Acta 57- Suzuki, K. Experimental alteration of molybdenite: evaluation of the Re-Os system, infrared spectroscopic profile and polytype. Geochim Cosmochim Acta 64- Acta 67- Selby, D. Acta 68- Dean, D. Thesis, University of Arizona, Tucson Arizona, pp.

Timing and formation of porphyry Cu-Mo mineralization in the Chuquicamata district, northern Chile: new constraints from the Toki cluster. Deposita 48- Voudoris, P. Ciobanu, C.

Re - Os dating and oil - source rock correlation is actually helped if the oils are highly biodegraded, e.g., oil sands, tar mats and bitumen-stained sandstones (where traditional techniques such as biomarker identification are disrupted), as this concentrates Re and Os within an oil making analysis easier. 3.

Trace element heterogeneity in molybdenite fingerprints stages of mineralization. Grabezhev, A. Shore, M. Oscillatory zoning in minerals: a common phenomenon.

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Watson, E. Surface enrichment and trace-element uptake during crystal growth. Acta 60- Holten, T. Noise and oscillatory zoning of mineral. Acta 64- Harvey, J. An overview of the platinum-group element nanoparticles in mantle-hosted chromite deposits.

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Ore Geol. Reich, M.

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Thermal behavior of metal nanoparticles in geologic materials. Barker, S. Acta 74- Xiong, Y. Experimental determination of the solubility of ReO 2 and the dominant oxidation state of rhenium in hydrothermal solutions. Berzina, A. Kusiak, M.

GEOCHRONOLOGY - PowerPoint PPT Presentation

Mobilization of radiogenic Pb in zircon revealed by ion imaging: Implications for early Earth geochronology. Geology 41- Valley, J. Hadean age for a post-magma-ocean zircon confirmed by atom-probe tomography. Metallic lead nanospheres discovered in ancient zircons. USA- Donovan, J. An improved mean atomic number correction for quantitative microanalysis. J Micros 2 Armstrong, J. Newberry, D. An improved interference correction for trace element analysis.

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Microbeam Analysis 2 Download references. This work was funded by Project Fondecyt to F.

Re-Os dating method was applied to the Kuroko ores from of the Wanibuchi Mine, southwestern Ja-pan. Two whole-rock Kuroko ores and two yellow color fragments separated from one Kuroko ore sample were analyzed. Their Re and Os concentrations range from to ppb and from to ppt. Nov 22,   These unique characteristics explain why Re-Os molybdenite dating using the whole mineral approach is currently the most widely used single Cited by: 4. mantle. Therefore, crustal rocks have high Re/Os , and crust therefore has higher Os/Os ratios than the mantle. Upper continental crust Re/Os Os/Os Lower continental crust (Lewisian Complex, Scotland) Re/Os Os/Os Mantle Re/Os ; Thus, there is a strong contrast in Os isotope.

Correspondence to Fernando Barra. Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

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Reprints and Permissions. Dissecting the Re-Os molybdenite geochronometer. Sci Rep 7, Download citation. Received : 15 September Accepted : 06 November Published : 22 November Mineralogical Magazine Minerals Mineralium Deposita By submitting a comment you agree to abide by our Terms and Community Guidelines.

If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate. Advanced search. Skip to main content. Register your interest. Subjects Geochemistry Mineralogy.

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Download. Introduction Ore deposits are the main source of metals for society, and their efficient and sustainable exploration requires a precise understanding of the factors that control their distribution within the upper crust.

Figure 1. Full size image. Figure 2.

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Figure 3. Figure 4. Discussion Distribution of noble metals in ore minerals Heterogeneous Re distribution, including oscillatory zoning, and Re-rich overgrowths in molybdenite crystals have been previously reported 151617although the mechanisms controlling the Re distribution remain poorly understood.

Controls on the incorporation of Re and Os in molybdenite Rhenium and Os are heterogeneously distributed reflecting changes in the composition of the hydrothermal fluid.

Re-os dating ppt

Parent-daughter isotope decoupling Published studies have shown diffusion of radiogenic Pb in the zircon structure and formation of Pb nanoparticles 2829 References 1. Article Google Scholar CAS Google Scholar The information presented below briefly outlines how Chemostrat is utilising two of these techniques, i.

Re and Os become concentrated in the organic, hydrogenous fraction of organic rich shales, thus the time when the shale was deposited can be dated.

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Furthermore, as Re and Os have been inherited from the source rocks, Os isotopes can be employed to correlate an oil with its source. Despite this application mainly being associated with the economic extraction of minerals, it can be employed by the oil and gas industry to date the formation of disseminated sulphide minerals within basement rocks and so the basement itself.

Moreover, when these minerals are found in fractures it can be used to provide a minimum date for when the fracture network was open.

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